Key Result – The phase can be Lorentz-transformed, but the Schrödinger dispersion relation is not Lorentz invariant.

Start with the free-particle Schrödinger plane wave:ψ(x,t)=Aei(kxωt)\psi(x,t)=A e^{i(kx-\omega t)}ψ(x,t)=Aei(kx−ωt)

Using de Broglie relations,p=k,E=ωp=\hbar k,\qquad E=\hbar \omegap=ℏk,E=ℏω

soψ(x,t)=Aei(pxEt)\psi(x,t)=A e^{\frac{i}{\hbar}(px-Et)}ψ(x,t)=Aeℏi​(px−Et)

For the nonrelativistic Schrödinger equation,E=p22mE=\frac{p^2}{2m}E=2mp2​

soω=k22m\omega=\frac{\hbar k^2}{2m}ω=2mℏk2​

Now apply a Lorentz transformation along the xxx-axis:x=γ(x+vt)x=\gamma(x’+vt’)x=γ(x′+vt′)t=γ(t+vxc2)t=\gamma\left(t’+\frac{v x’}{c^2}\right)t=γ(t′+c2vx′​)

whereγ=11v2/c2\gamma=\frac{1}{\sqrt{1-v^2/c^2}}γ=1−v2/c2​1​

Substitute these into the phase:pxEt=pγ(x+vt)Eγ(t+vxc2)px-Et = p\gamma(x’+vt’) – E\gamma\left(t’+\frac{vx’}{c^2}\right)px−Et=pγ(x′+vt′)−Eγ(t′+c2vx′​)

Collect terms in xx’x′ and tt’t′:pxEt=γ(pvEc2)x+γ(pvE)tpx-Et = \gamma\left(p-\frac{vE}{c^2}\right)x’ + \gamma(pv-E)t’px−Et=γ(p−c2vE​)x′+γ(pv−E)t′

Rewrite it aspxEt=pxEtpx-Et = p’x’-E’t’px−Et=p′x′−E′t′

so we identifyp=γ(pvEc2)\boxed{ p’=\gamma\left(p-\frac{vE}{c^2}\right) }p′=γ(p−c2vE​)​

andE=γ(Evp)\boxed{ E’=\gamma(E-vp) }E′=γ(E−vp)​

Therefore the transformed wave isψ(x,t)=Aei(pxEt)\boxed{ \psi'(x’,t’) = A e^{\frac{i}{\hbar}(p’x’-E’t’)} }ψ′(x′,t′)=Aeℏi​(p′x′−E′t′)​

orψ(x,t)=Aei(kxωt)\boxed{ \psi'(x’,t’) = A e^{i(k’x’-\omega’t’)} }ψ′(x′,t′)=Aei(k′x′−ω′t′)​

withk=γ(kvωc2)\boxed{ k’=\gamma\left(k-\frac{v\omega}{c^2}\right) }k′=γ(k−c2vω​)​

andω=γ(ωvk)\boxed{ \omega’=\gamma(\omega-vk) }ω′=γ(ω−vk)​

So the phase transforms nicely:kxωt=kxωtkx-\omega t = k’x’-\omega’t’kx−ωt=k′x′−ω′t′

However, here is the important point.

For the Schrödinger wave,ω=k22m\omega=\frac{\hbar k^2}{2m}ω=2mℏk2​

But after Lorentz transformation,ω=γ(ωvk)\omega’=\gamma(\omega-vk)ω′=γ(ω−vk)k=γ(kvωc2)k’=\gamma\left(k-\frac{v\omega}{c^2}\right)k′=γ(k−c2vω​)

In general,ωk22m\boxed{ \omega’ \neq \frac{\hbar k’^2}{2m} }ω′=2mℏk′2​​

So the transformed wave is not generally another valid Schrödinger plane wave with the same nonrelativistic dispersion relation.

That is the core result:The phase pxEt can be Lorentz transformed, but the Schro¨dinger equation itself is not Lorentz invariant.\boxed{ \text{The phase } px-Et \text{ can be Lorentz transformed, but the Schrödinger equation itself is not Lorentz invariant.} }The phase px−Et can be Lorentz transformed, but the Schro¨dinger equation itself is not Lorentz invariant.​

For Lorentz invariance, the energy relation must be relativistic:E2=p2c2+m2c4\boxed{ E^2=p^2c^2+m^2c^4 }E2=p2c2+m2c4​

which leads to the Klein-Gordon equation for scalar particles or the Dirac equation for spin-12\frac1221​ particles.